How-to: Link 2 Hotmail accounts / Windows Live IDs
You have more than one Windows Live ID — for example one in the office and one privately? You can link both with each other. If you do that, you can sign in at a Windows Live website like Hotmail once and access information in both accounts.
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Open http://home.live.com/ in your browser.
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Sign in with your first Windows Live ID.
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On the top right, click on your account name. A drop-down menu appears.
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In the menu, click the Link other accounts entry.
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You may be asked to re-enter your Windows Live password.
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Click the Link an existing Windows Live ID hyperlink.
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Enter the password of your first Windows Live ID, and the e-mail address as well as the password for the second Windows Live ID, the one you are going to link.
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Click the Link button.
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Now on the top right, click your name. You can access both linked accounts from there now — without additional sign-in.